Storage Engineering, Material Handling & Packaging

Agricultural Engineering · Post-Harvest, Food & Process Engineering · also Storage Systems, Material Handling, Packaging and Transport

13units
12chapters
7,965words
144practice questions

Storing grain and produce safely, the loads it puts on bins and silos, and the conveyors and packages that move and protect it.

In the exams: GATE AG Section 6 (bin/silo pressure in 6 of 8 papers 2019–26); ICAR AICE subject 41 Units 6–7; NCEES PE (ANSI/ASAE S433 supplied); ASRB NET ASPE

Syllabus

  1. Causes of storage losses
  2. Bag and bulk storage
  3. Godowns and warehouses
  4. Bins and silos
  5. Janssen's and Airy's theories of bin pressure
  6. Aeration of stored grain
  7. Fumigation
  8. Controlled and modified atmosphere storage
  9. Warehouse management
  10. Packaging materials: paper, plastics and laminates
  11. Barrier properties of packages
  12. Packaging machines
  13. Design of conveyors and elevators

Study manual

Storage engineering, material handling and packaging is the part of agricultural process engineering that keeps a harvested crop safe, whole and saleable between the farm and the consumer. Grain is harvested once or twice a year but eaten every day, so most of it sits in a bag, a godown, a bin or a silo for months. Between every store and every process the material has to be moved, by belt, screw, bucket, chain or air. This subject covers all three: the stores, the loads they carry, the atmosphere inside them, the packages that protect food on its way out, and the conveyors that move it.

The engineering is concrete. A bin wall must carry the lateral pressure of the grain and the friction the grain drags down the wall, and it fails if the designer uses the hydrostatic pressure of a liquid instead of Janssen's equation, or ignores the extra load during discharge. An aeration fan must deliver a set airflow per tonne against the resistance of the grain bed. A fumigation must hold a lethal gas concentration long enough, in a sealed enclosure, without poisoning the people outside. A laminate must keep water vapour or oxygen out for the shelf life printed on the pack.

Examinations treat the subject in two ways. Numerical papers such as GATE Agricultural Engineering repeatedly ask for Janssen and Rankine bin pressures, the shallow or deep classification of a bin, silo capacity from bulk density, bucket-elevator speed, conveyor capacity and package permeation. Recall papers such as ICAR AIEEA-PG and ASRB NET ask for storage pests, godown and CAP storage practice, fumigants, CA and MA storage, packaging polymers and packaging machines. Licensing examinations such as the NCEES PE Agricultural and Biological Engineering supply the relevant standard for grain loads on bins and expect the candidate to apply it; the Philippine ABELE draws on national agricultural engineering standards. Practice, pesticide registration and warehouse law differ from country to country, and the manual says so where it matters.

1. 1. Causes of storage losses and the stored-grain ecosystem

Grain is alive, and so is everything in it

A store of grain is an ecosystem, not an inert heap. The kernels themselves respire slowly, consuming carbohydrate and oxygen and releasing carbon dioxide, water and heat. The kernels, and the insects, mites and fungi that live among them, are all controlled by the same few physical variables: grain moisture content, the relative humidity of the air between the kernels (called the equilibrium relative humidity, ERH, because the air comes into equilibrium with the grain), grain temperature, and the oxygen and carbon dioxide in the intergranular air. Losses are of two kinds. Quantitative loss is lost mass: kernels eaten by insects and rodents, dry matter respired by grain and moulds, spillage from torn bags. Qualitative loss is lost value without much lost mass: discoloured, sprouted or broken kernels, insect fragments and excreta, off-odours, reduced germination in seed, and mycotoxins produced by moulds.

Biotic causes: insects, mites, fungi, rodents and birds

Stored-product insects are grouped by how they feed. Primary (internal) feeders can attack whole, sound kernels, and their larvae develop hidden inside the grain; examples are the rice weevil and maize weevil (Sitophilus species), the lesser grain borer (Rhyzopertha dominica), the Angoumois grain moth (Sitotroga cerealella), and in pulses the pulse beetles or bruchids (Callosobruchus species). Secondary (external) feeders cannot easily breach an intact kernel and multiply on broken grain, dust, flour and kernels already damaged; examples are the red flour beetle (Tribolium castaneum), the saw-toothed grain beetle (Oryzaephilus surinamensis) and the rice moth (Corcyra cephalonica). Insects multiply fastest in warm grain, roughly in the range of the mid-twenties to mid-thirties degrees Celsius, and development slows sharply as grain cools towards the mid-teens; the exact limits differ by species. Fungi are divided into field fungi (for example Fusarium and Alternaria), which invade the crop before harvest and need very high moisture, and storage fungi (mainly Aspergillus and Penicillium species), which grow at lower moisture in the store. Storage fungi need an intergranular relative humidity of roughly 65 to 70 per cent or more; below that, grain can be kept for long periods. Some Aspergillus species produce aflatoxins, and Penicillium and Aspergillus species produce ochratoxin A; Fusarium species produce toxins such as deoxynivalenol and fumonisins in the field.

Abiotic causes and grain respiration

Moisture and temperature are the abiotic drivers. Safe storage moisture depends on the crop, the temperature and the intended storage period: cereals are commonly stored at about 12 to 14 per cent wet basis in temperate conditions and nearer the lower end in warm climates, while oilseeds, which hold their water in a smaller non-oil fraction, must be stored drier. Respiration of grain and of the organisms in it can be written with glucose as the substrate: C6H12O6 + 6 O2 → 6 CO2 + 6 H2O + about 2.8 MJ per mole of glucose. Per kilogram of dry matter oxidised this is roughly 15.7 MJ of heat, 0.6 kg of water and 1.47 kg of carbon dioxide. The rate of dry matter loss is often used as an index of storability: in drying and storage research on maize, a dry matter loss of about 0.5 per cent has been used as the limit of acceptable quality, and allowable storage time charts are built on it. Mechanically damaged and stress-cracked kernels deteriorate faster.

Measuring and reducing losses

Storage loss is measured by drawing representative samples with a probe (spear) from many points in a stack or bin and determining the proportion of damaged kernels and the weight loss; the count-and-weigh method compares the mean mass of damaged and undamaged kernels in a sample to estimate the mass lost. Dry the grain to a safe moisture before storage; clean it to remove broken kernels, dust and weed seed, which carry pests and resist airflow; cool it by aeration so that insects and moulds are slowed; store it in a structure that excludes rain, ground moisture, rodents and birds; seal it when fumigation or hermetic storage is used; monitor temperature, moisture and carbon dioxide; and rotate stock so that nothing sits longer than it can safely be kept. Together these form integrated pest management for stored products, which matters because phosphine resistance is now common in several major stored-product insects.

Remember

2. 2. Bag and bulk storage systems

Traditional and farm-level storage

Most of the world's grain is still stored by farmers in small quantities. Traditional structures of mud, bamboo, straw or brick often admit ground moisture and rain, cannot be sealed, and let rodents and insects in. Improved farm structures address these faults with a raised base, a damp-proof floor, rodent guards, a tight lid and a discharge outlet at the bottom so that the oldest grain leaves first.

Bag storage

In bag storage grain is filled into jute (hessian), woven polypropylene or high-density polyethylene bags, commonly of 50 kg in many countries, and the bags are stacked on dunnage in a warehouse or on a plinth in the open. The advantages of bags are flexibility and traceability: lots of different owners or qualities stay separate, and bags can be counted, inspected and moved by hand or on pallets. The disadvantages are labour cost, bag cost and bag deterioration, spillage from torn bags, the large surface through which insects enter and cross-infest, the difficulty of monitoring the inside of a stack, and slower handling than bulk. Bags are stacked in a bonded pattern (alternate layers laid crosswise, like brickwork) so that the stack is stable, with a set maximum height, gangways between stacks for inspection, fumigation and movement, and a clear space between the stacks and the walls so that rodents can be seen and the walls do not wet the grain. Dunnage, a layer of wooden crates, pallets or plastic sheet under the stack, keeps the bottom bags off a floor that can transmit moisture.

Bulk storage

In bulk storage grain is held loose in bins, silos, bunkers or flat stores and moved by conveyors. Bulk storage uses space better, avoids bag cost, allows mechanical handling at high rates, and allows aeration, temperature monitoring and fumigation of the whole mass from outside. It needs capital for structures and conveyors, grain that is uniformly dry and clean, and good management, because a problem in a bulk store affects a large mass at once and cannot be removed bag by bag. Bunkers (covered piles on a pad) and silo bags (long multilayer polyethylene tubes filled in the field) are low-cost temporary bulk stores, vulnerable to puncture and wet grain.

Choosing bag or bulk

The engineering decision between bag and bulk is a comparison of annual cost per tonne and of risk. Bag storage has low capital cost and high running cost (bags, labour, fumigation of stacks, handling losses); bulk storage has high capital cost and low running cost per tonne, and becomes cheaper at high throughput. In several countries public procurement agencies have moved from bags in godowns and cover-and-plinth storage towards bulk steel silos for wheat and rice at large procurement centres, with bags kept for distribution.

Remember

3. 3. Godowns, warehouses and cover-and-plinth storage

What a godown must do

A godown or warehouse is a covered building for storing bagged or packed produce. Whatever the local design code, a sound godown for food grain does six things. It keeps out rain and ground moisture, through a raised plinth, a damp-proof course and a floor that does not wick water. It keeps out rodents, through a plinth high enough and smooth enough that rats cannot climb it, rodent-proof doors that close tightly, a projecting rat-proof course, no gaps at the eaves, and wire mesh on ventilators. It keeps out birds, through meshed openings. It can be closed tightly for fumigation of the whole building or, more usually, individual stacks under gas-proof covers. It allows ventilation in dry weather and closure in humid weather, through ventilators that can be shut. And it limits heat gain, through reflective or insulated roofing and adequate roof overhang.

Layout and capacity

The capacity of a godown is determined by the floor area actually available for stacks, the stack height and the bulk density of the bagged grain. Floor area for stacks is the gross area less gangways, wall clearance and working space. Stacks are laid out on marked plots so that every stack can be reached for inspection, sampling and fumigation, and so that the first-in, first-out principle can be followed. Bag stacks are usually limited in height by stability, labour and the load on the floor; the permitted height depends on the agency code. A useful first estimate of capacity is: mass stored = number of stacks × bags per stack × mass per bag, with bags per stack = (bags along length) × (bags across width) × (layers).

Cover-and-plinth (CAP) storage

Cover-and-plinth storage is an open-air method widely used in South Asia for temporary storage of procured grain. Bags are stacked on a raised plinth of brick or concrete, laid on dunnage, and covered with low-density polyethylene covers, the covers being tied down with ropes and nets against wind. Its risks are high: covers tear, rain penetrates, condensation forms under the cover when nights are cold, birds and rodents attack from the edges, and quality deteriorates faster than in a godown. Good practice includes a plinth higher than local flood level, a slope on the stack top so rain runs off, sound covers checked after every storm, periodic aeration by opening the covers in dry weather, and early movement of the oldest stocks.

Remember

4. 4. Bins and silos: types, capacity and flow

Definitions and types

A bin or silo is a vertical container for bulk material. By construction, bins are made of corrugated galvanised steel sheet on a concrete foundation, bolted steel with hopper bottoms, reinforced concrete (cast in place, often by slip-forming for tall silos), masonry, or ferro-cement for small units. By base, they are flat-bottomed, standing on a slab and emptied partly by gravity through centre and intermediate sumps and finally by a sweep auger, or hopper-bottomed, with a conical hopper that empties completely by gravity. Flat-bottomed steel bins with a perforated aeration floor are common for large on-farm and commercial storage; hopper-bottom bins are used for short-term holding and where complete, fast discharge matters.

Capacity from dimensions and bulk density

The capacity of a bin is its grain volume multiplied by the bulk density of the grain. Bulk density is the mass of a bulk sample divided by the total volume it occupies, including the pores between the kernels; it is lower than the kernel (true) density by the factor (1 − porosity). Typical bulk densities are roughly 750 to 800 kilograms per cubic metre for wheat, a little lower for maize, and lower again for paddy and oats, but they vary with variety, moisture content, foreign matter and the way the bin is filled, so always use a measured or tabulated value for the actual crop. For a cylindrical bin of diameter D filled to an eave height H, the cylinder volume is πD²H/4. If the grain is heaped at its angle of repose θr above the eave, the heap is a cone of height (D/2)tanθr and volume πD²h/12. A conical hopper of height h below the cylinder adds another πD²h/12. Grain also packs down under its own weight in a tall bin, so the average bulk density in a full bin exceeds the loose-fill value; standards provide packing factors for this effect.

Flow patterns in bins and hoppers

When a bin is emptied, grain does not flow uniformly. In funnel flow (core flow) only a central channel above the outlet moves; the grain against the walls stays still until the channel has drained, and then slides in from the top. Funnel flow is first-in, last-out, lets old grain remain against the walls, can leave stagnant zones, and with cohesive materials can form a stable empty channel called a rathole. In mass flow the whole contents move together whenever any grain is drawn, which gives first-in, first-out discharge, uniform residence time and predictable wall loads, but needs a steep, smooth hopper. Whether a hopper gives mass or funnel flow depends on its wall angle from the vertical and the wall friction angle between the material and the hopper surface; Jenike's method, based on shear-cell tests of the bulk solid, gives the limiting hopper angle and the minimum outlet size to prevent a cohesive arch forming over the outlet. Eccentric discharge, from an outlet not at the centre, creates non-uniform wall pressures around the circumference and is a known cause of silo failure; it must be avoided or designed for.

Structural and operational points

A cylindrical bin wall carries lateral grain pressure mainly as hoop tension: for a thin wall, the tension per unit height is p·D/2, where p is the lateral pressure at that depth, so the required sheet thickness or reinforcing steel increases with depth and is greatest near the bottom of the wall (deep bins approach a limiting pressure, as chapter 5 shows). The wall also carries a vertical compressive load from grain friction transferred to it, which can buckle thin steel walls, which is why steel bins have vertical stiffeners. Operation brings safety hazards. People have died by entrapment when they entered a bin with an unloading auger running, stood on crusted grain that bridged over a void, or were engulfed by a collapsing grain wall. Grain dust in elevators and silos is explosive when suspended in air near an ignition source. Standard practice is to lock out unloading equipment, never walk on grain during unloading, use a harness, lifeline and outside attendant, and test the atmosphere before entry.

Remember

5. 5. Grain pressure on bin walls: Rankine, Janssen and Airy

Why grain is not a liquid

Grain differs from a liquid in two ways. First, the lateral pressure at a point is only a fraction k of the vertical pressure; k is called the ratio of lateral to vertical pressure. Second, part of the grain's weight is carried by friction on the wall rather than by the grain below, so in a tall bin the vertical pressure stops increasing linearly and approaches a limit. The bin geometry enters through the hydraulic radius R, which is the cross-sectional area divided by the perimeter: for a circular bin of diameter D, R = D/4; for a square bin of side a, R = a/4; for a rectangular bin, R = ab/(2(a + b)).

Shallow and deep bins

Bins are classified as shallow or deep by where the plane of rupture meets the grain. Rankine's theory, taken from soil mechanics, places the plane of rupture of a failing wedge at an angle θ = 45° + φ/2 to the horizontal. Drawn upward from the base of one wall, this plane either reaches the grain surface before it reaches the opposite wall, and the bin is shallow, or it strikes the opposite wall first, and the bin is deep. For a bin of width or diameter D and grain depth H, this gives the commonly used textbook criterion: the bin is shallow if H < D·tan(45° + φ/2) and deep if H is greater. Different standards and textbooks use other criteria, for example a limiting ratio of height to diameter, so state which criterion is being applied.

Rankine's theory for shallow bins

For a shallow bin with a level grain surface and a frictionless vertical wall, Rankine's active earth-pressure theory gives the lateral pressure at depth h as L = γh·k, where k = (1 − sinφ)/(1 + sinφ) = tan²(45° − φ/2). The pressure increases linearly with depth, like a liquid but reduced by k. The total lateral force on a unit length of wall of height H is the area of the triangular pressure diagram, P = γH²k/2, acting at H/3 above the base. The vertical pressure on the floor of a shallow bin is taken as the full weight of grain per unit area, γH, because wall friction carries little.

Janssen's theory for deep bins

Janssen (1895) considered a thin horizontal slice of grain of thickness dh at depth h in a bin of area A and perimeter C. The forces on it are its weight γA·dh, the vertical pressure V·A from above and (V + dV)·A from below, and the friction on the wall μ′·L·C·dh, where L = kV is the lateral pressure. Equilibrium gives dV/dh = γ − μ′kV/R with R = A/C. Integrating with V = 0 at the surface gives the Janssen equations: V = (γR/(μ′k))·(1 − e^(−μ′kh/R)) for vertical pressure and L = kV = (γR/μ′)·(1 − e^(−μ′kh/R)) for lateral pressure. As depth increases the exponential term vanishes and the pressures approach limits: V_max = γR/(μ′k) and L_max = γR/μ′. The lateral limit is independent of k: it depends only on specific weight, hydraulic radius and wall friction. In a practical bin the pressure reaches about 95 per cent of its limit when μ′kh/R = 3, that is, at a depth of 3R/(μ′k). The value of k used in Janssen's equation is commonly taken from Rankine's expression, but it can also be measured; design standards for grain bins specify how to choose k and μ′ and add overpressure factors for discharge, and the current edition of the standard must be used for design.

Airy's theory and wall loads

Airy (1897) analysed the wedge of grain that would slide along a plane of rupture, including friction between the grain and the wall as well as internal friction, and chose the plane that makes the wall force greatest. For a shallow bin his result for the total lateral force per unit length of wall of height h is P = (γh²/2)·[1/(√(μ(μ + μ′)) + √(1 + μ²))]². When wall friction is zero (μ′ = 0) this reduces exactly to Rankine's γh²k/2, which is a useful check. Because wall friction supports part of the wedge, Airy's shallow-bin force is smaller than Rankine's when μ′ > 0. Two quantities follow directly from the Janssen solution and are often asked. The load on the floor of a deep bin is V·A, which is less than the total grain weight; the difference, W − V·A, is the total friction force carried by the wall and passed to the wall foundation. And the hoop tension in a circular wall at depth h is L·D/2 per unit height. Discharge, eccentric flow, grain swelling and thermal contraction of the wall in cold nights can all raise wall pressures above the static Janssen values, which is why standards apply overpressure factors.

Remember

6. 6. Aeration of stored grain and moisture migration

Purpose of aeration

Aeration is the forced movement of ambient air through stored grain at low airflow rates to control grain temperature. It is not drying. Drying uses high airflow, often heated air, to remove large amounts of water in days; aeration uses airflow roughly an order of magnitude or more lower, with unheated air, to cool the grain, make its temperature uniform, remove odours and fumigant residues, and prevent moisture migration. Aeration airflow is expressed per unit of grain: cubic metres of air per minute per tonne (m³ min⁻¹ t⁻¹), or in the United States cubic feet per minute per bushel.

Moisture migration

In a bin of grain that has been stored warm going into a cold season, the grain near the walls and the top cools while the centre stays warm, because grain is a poor conductor of heat. The air in the intergranular spaces then begins to circulate by natural convection: cold, dense air near the wall sinks down along the wall, moves toward the centre at the bottom, is warmed by the warm central grain and rises up the centre. The rising warm air carries moisture picked up from the warm grain. When it reaches the cold grain near the top centre it is cooled below its dew point and deposits water there. The result is a wet, crusted layer a short distance below the top centre of the bin, where moulds grow and grain sprouts. In a warm season the pattern reverses: the walls warm, air rises along the walls and descends through the cooler centre, and moisture accumulates near the bottom centre. Moisture migration can spoil grain that went into the store at a safe average moisture content, because the problem is redistribution, not the total amount of water. Aeration prevents it by keeping the temperature across the bin uniform, so there is no temperature difference to drive convection.

Cooling fronts and managing the fan

When aeration air enters a bin at a temperature different from the grain, the grain does not change temperature everywhere at once. A cooling (or warming) front forms and moves through the grain in the direction of airflow; grain behind the front is at the air temperature and grain ahead of it has not yet changed. Because grain has a far higher volumetric heat capacity than air, the front moves much more slowly than the air itself, and a cycle can take tens to hundreds of hours depending on the airflow rate. A cycle must be completed: stopping the fan when the front is half-way through leaves a boundary of warm and cool grain, which can drive local condensation. Aeration controllers switch the fan on only when the ambient air is suitably cooler than the grain and not so humid that it would wet the surface grain; the temperature difference at which to start and the humidity limits vary by climate and are set by local recommendations.

Fan and duct design

Aeration design proceeds in four steps. First, choose the airflow rate per tonne and multiply by the mass of grain to get the total airflow Q. Second, find the superficial air velocity, Q divided by the cross-sectional area of the bin, and use it with airflow-resistance data to get the static pressure drop per metre of grain depth. The standard airflow-resistance data for grains, based on Shedd's measurements, give pressure drop as a function of superficial velocity for each grain; in the relation commonly used, the pressure drop per unit depth is a·Q²/ln(1 + b·Q), where Q is superficial airflow and a and b are grain-specific constants. Fines and packing raise resistance, and design practice multiplies the clean-grain value by a packing factor. Multiply by grain depth and add duct, floor and transition losses to get the total static pressure. Fourth, compute power: the air power is Q·Δp (m³/s × Pa = W), and the shaft power is Q·Δp divided by the fan efficiency. Because pressure drop rises faster than linearly with airflow, and depth multiplies it, doubling grain depth at a fixed airflow per tonne roughly doubles both the superficial velocity and the depth, raising the pressure several-fold; deep bins therefore need much more fan power per tonne than shallow ones at the same airflow per tonne.

Remember

7. 7. Fumigation

What a fumigant is

A fumigant is a chemical that acts as a gas at the temperature of use and penetrates a commodity to kill pests in all their stages, including those hidden inside kernels, which contact insecticides applied to surfaces cannot reach. Two fumigants have dominated grain storage. Methyl bromide was widely used for grain, structures and quarantine, but it depletes stratospheric ozone and its production and use have been phased out under the Montreal Protocol, apart from exemptions such as quarantine and pre-shipment treatments in some countries, which are themselves being reduced. Phosphine (hydrogen phosphide, PH3) is now the principal grain fumigant worldwide. It is generated in place from solid metal phosphides, mainly aluminium phosphide and magnesium phosphide formulated as tablets, pellets or sachets, which react with moisture in the air: AlP + 3 H2O → Al(OH)3 + PH3. Which fumigants may be used on which commodities, at what dose and exposure time, and by whom, is controlled by each country's pesticide regulator and the product label, and the label always governs.

Concentration, time and the CT product

The effect of a fumigant depends on the concentration held in the enclosure and on how long it is held. The concentration–time (CT) product is used to compare treatments, but for phosphine the exposure time matters more than the concentration: phosphine acts slowly, and the egg and pupal stages are tolerant, so a long exposure at moderate concentration kills better than a short exposure at high concentration. Exposure periods for phosphine are therefore measured in days, and they lengthen at low temperatures, when insects are less active and the fumigant less effective. Concentrations are measured in parts per million by volume or in grams per cubic metre. To convert, mg/m³ = ppm × M/Vm, where M is the molar mass of the gas (34.0 g/mol for PH3) and Vm is the molar volume of an ideal gas at the temperature and pressure of the enclosure, about 24.45 L/mol at 25 °C and one atmosphere. The quantity of phosphine released by a metal phosphide formulation follows from the reaction stoichiometry: one mole of aluminium phosphide (about 58 g) yields one mole of phosphine (about 34 g), so a 3 g tablet containing about 56 per cent aluminium phosphide releases roughly 1 g of phosphine.

Sealing and the enclosure

A fumigation is only as good as its seal. Phosphine is a small molecule that leaks through gaps, porous walls and unsealed covers, and a leaky enclosure never reaches or holds a lethal concentration, however much fumigant is applied. Under-dosing and leaky enclosures are the main causes of the rapid development of phosphine resistance in insect populations. Bag stacks are fumigated under gas-proof covers (fumigation covers of plasticised or laminated sheet) with the edges sealed to the floor with sand snakes; godowns and silos must be sealed at doors, vents and conveyor openings. The gas-tightness of a sealed silo is tested by a pressure-decay test: the silo is pressurised by a small amount and the time for the pressure to fall to half is measured, and a minimum half-life is required for effective fumigation; the test pressures and required times are specified by the storage authority. After exposure, the enclosure is ventilated and the concentration must fall below the permitted level before people re-enter and before the grain is handled or dispatched.

Safety

Phosphine is highly toxic to people by inhalation, and aluminium phosphide is highly toxic if swallowed; deaths occur every year from accidental exposure and from misuse. Pure phosphine is said to be odourless; the garlic or fish-like odour of technical phosphine comes from impurities and cannot be relied on to warn of danger. Phosphine can ignite spontaneously in air at concentrations above its lower flammability limit, about 1.8 per cent by volume, which is why metal phosphides must not be piled together, must not contact liquid water, and the spent residue must be handled as instructed. Phosphine corrodes copper, brass, silver and gold, damaging electrical equipment and electronics in a fumigated space. Permitted occupational exposure limits and re-entry concentrations are set by national regulators; check the current national value.

Remember

8. 8. Controlled, modified and hermetic atmosphere storage

Principles

Controlled atmosphere (CA) and modified atmosphere (MA) storage change the gas composition around a stored product, usually by lowering oxygen and raising carbon dioxide, to slow respiration, ripening and the activity of pests. In controlled atmosphere storage the composition is measured and actively regulated throughout storage, by adding nitrogen, scrubbing carbon dioxide and admitting air as needed. In modified atmosphere storage the atmosphere is changed at the start, by gas flushing or by the respiration of the product itself, and then allowed to evolve, with no active control; modified atmosphere packaging applies the same idea to consumer packs. Hermetic storage is a form of modified atmosphere in which a gas-tight container is sealed and the respiration of the grain, insects and fungi inside consumes oxygen and produces carbon dioxide until insects die or become inactive. All three need a well-sealed enclosure; without it, air leaks in and the atmosphere reverts.

Grain and dry commodities

For grain, pulses and dried products, the aim is to kill or suppress insects without chemical residues. Insects are killed by very low oxygen (commonly an oxygen content below about 1 per cent is targeted in nitrogen treatments) or by high carbon dioxide (typically several tens of per cent), held for a period that ranges from several days to several weeks depending on temperature, species and life stage; exact treatment schedules are set by the storage authority. Nitrogen is supplied from liquid nitrogen or generated on site by pressure-swing adsorption or membrane separation of air. Hermetic storage for smallholders uses multilayer polyethylene bags, sometimes with an inner high-barrier liner, or rigid hermetic containers, in which oxygen falls and carbon dioxide rises within days to weeks as the biological activity of the contents consumes the oxygen. Their performance depends on the grain being dry, the bag being sealed carefully and not punctured, and on the bag material having low oxygen permeability.

Fruit and vegetables

Fresh produce is alive and must keep respiring aerobically. Lowering oxygen to a few per cent and raising carbon dioxide slows respiration, delays ripening and softening, reduces sensitivity to ethylene, and can reduce some physiological disorders and decay. Below a lower oxygen limit, which differs by commodity and cultivar, the produce switches to anaerobic respiration and develops off-flavours from ethanol and acetaldehyde; above a carbon dioxide tolerance limit, some produce suffers injury. The optimum atmosphere is therefore species-specific and often cultivar-specific, and published recommendations (for example in postharvest handbooks) should be followed. Controlled atmosphere stores for apples and pears are gas-tight insulated rooms with refrigeration, nitrogen generators or other means to pull down oxygen, carbon dioxide scrubbers (using activated carbon, hydrated lime or molecular sieves), and often ethylene removal by catalytic oxidation or permanganate absorbers. CA supplements refrigeration and never replaces it.

Modified atmosphere packaging

In modified atmosphere packaging (MAP) of fresh produce, the equilibrium atmosphere inside a sealed pack is set by a balance between the respiration of the produce and the permeation of gases through the film. At steady state, the oxygen consumed by the produce (respiration rate times mass) equals the oxygen entering through the film, which is the film's oxygen permeance times its area times the oxygen partial-pressure difference across it. The same balance holds for carbon dioxide leaving. Because respiration rate varies strongly with temperature and permeability varies less, a pack designed for one temperature may become anaerobic when warmed, so MAP depends on a controlled cold chain. For non-respiring foods such as meat, cheese, bakery and snacks, MAP means flushing the pack with a chosen gas mixture, commonly carbon dioxide to inhibit microbes and nitrogen as an inert filler, in a high-barrier package, so that the atmosphere stays as set.

Remember

9. 9. Warehouse management

Receiving and recording

Warehouse management keeps the stock in the quantity and quality recorded for it, at the lowest cost, and gives the owner and the lender confidence in the record. It begins at receipt. Every lot is weighed on a calibrated weighbridge or platform scale, sampled with a probe from a statistically adequate number of bags or points, and analysed for moisture, foreign matter, damaged and discoloured kernels, insect infestation and, where required, mycotoxins. Lots above the acceptable moisture or infestation limit are rejected, dried or fumigated before storage. Each stack or bin is given a stack card or electronic record showing the commodity, variety, grade, owner, date of receipt, number of bags and weight, and every treatment and inspection. Accounting for stock uses first-in, first-out (FIFO) rotation for commodities that deteriorate with age, or first-expired, first-out (FEFO) for packaged goods with expiry dates.

Storage hygiene and inspection

Most infestation in a warehouse comes from residues of old grain and from new grain that arrives infested. Hygiene before a new season therefore means cleaning the empty building thoroughly, removing spillage from corners, cracks and equipment, treating the empty structure with a registered residual insecticide or fumigant where permitted, and repairing damage to floors, walls and roofs. During storage, prophylactic treatments with registered contact insecticides may be applied to the surfaces of stacks and to the building, and curative fumigation is used when infestation is found. Regular inspection records stack temperature and moisture and looks for insects, heating, mould, rodent signs and leaks. Ventilation of godowns is managed by opening ventilators when the outside air is drier and cooler than the air inside, and closing them in wet or humid weather.

Weight changes and shrink

The weight of grain changes during storage even when nothing is stolen or eaten, because its moisture content changes. The dry matter is conserved, so if grain of initial mass m1 at moisture M1 (wet basis) comes to moisture M2, its new mass is m2 = m1·(1 − M1)/(1 − M2). Grain received wet and stored in a dry climate loses weight; grain received dry in a humid season can gain weight. Genuine losses from respiration, insects and handling come on top of this moisture shrink. When a depositor withdraws grain, the warehouse must deliver the quantity on the receipt adjusted according to the contract terms, so accurate moisture measurement at receipt and dispatch protects both parties.

Costs, capacity use and planning

The economics of a warehouse depend on its capacity utilisation, the proportion of available capacity actually occupied averaged over the year, and on its throughput, the number of times the capacity is turned over. Fixed costs (depreciation, interest, insurance, security, staff) are spread over the tonnes stored, so the cost per tonne falls as utilisation rises. Variable costs include handling labour, fumigation, insecticides, power for aeration and conveyors, and losses. Good records tell the manager when to sell, when to fumigate, and when stock has reached the end of its safe storage time.

Remember

10. 10. Packaging materials: paper, plastics, metals, glass and laminates

Functions of a package

A package contains the product, protects it, preserves it, makes it convenient to handle and use, and communicates information about it. Packaging is described at three levels: primary packaging is in direct contact with the food (a pouch, bottle or can); secondary packaging groups primary packs (a carton or shrink-wrapped tray); tertiary or transport packaging groups secondary packs for shipping (a pallet with stretch wrap). Materials in contact with food must comply with food-contact regulations, which limit the migration of constituents from the packaging into the food; the rules and approved substances differ by jurisdiction.

Paper and paperboard

Paper is a mat of cellulose fibres, made mainly from wood pulp. Kraft paper, made by the sulfate pulping process, is strong and used for multiwall sacks and bags for flour, sugar, cement and feed. Greaseproof paper has highly beaten fibres that resist oil; glassine is greaseproof paper that has been super-calendered to a dense, glossy, translucent sheet; vegetable parchment is paper treated with sulfuric acid to form a wet-strong, grease-resistant surface. Paperboard is thicker paper used for folding cartons; corrugated fibreboard consists of a fluted corrugating medium glued between linerboards, and its flute sizes are designated by letters, of which A flute is the tallest, followed by C, B and E in decreasing height. Paper and board are poor barriers to water vapour and gases and lose strength when wet; they are coated or laminated with polyethylene, wax or other polymers when a barrier is needed.

Plastics

Most flexible food packaging is plastic. Low-density polyethylene (LDPE) and linear low-density polyethylene (LLDPE) are flexible, tough and good heat-sealants with a good water-vapour barrier but a poor oxygen barrier. High-density polyethylene (HDPE) is stiffer, with a better moisture barrier, used for milk and juice bottles and woven sacks. Polypropylene (PP), often biaxially oriented (BOPP) for clarity and stiffness, is a good moisture barrier with a higher melting point than polyethylene, so cast PP is used as the sealant in retortable pouches. Polyethylene terephthalate (PET) is strong, clear and a moderate gas barrier, used for bottles and as the outer printed layer of laminates. Polyvinylidene chloride (PVDC) is a very good barrier to both water vapour and oxygen, used as a coating. Ethylene vinyl alcohol copolymer (EVOH) is an excellent oxygen barrier when dry but absorbs water and loses much of its barrier at high humidity, so it is always buried between moisture-resistant layers such as polyethylene or polypropylene. Polyamide (nylon) is tough and puncture-resistant with a good oxygen barrier. Polystyrene (PS) is used rigid for cups and foamed (expanded PS) for trays and insulated boxes.

Metals and glass

Metal cans are made of tinplate (steel coated with tin), tin-free steel (electrolytic chromium-coated steel), or aluminium, with internal lacquers to prevent reaction with the food. Cans are near-perfect barriers to gases, light and microorganisms, withstand retort sterilisation, and are closed by the double seam, in which the can end's curl and the body flange are interlocked in two rolling operations; seam dimensions are checked by teardown or sectioning. Aluminium foil is an excellent barrier in thicknesses where it is free of pinholes; very thin foils may have pinholes, and flexing can crack foil, which is why foil is laminated to plastics. Glass is inert, transparent, rigid and a total barrier to gases, but it is heavy and breakable and its closure is usually the weakest barrier point. Metallised films, plastic films with a very thin vapour-deposited layer of aluminium, and films with transparent oxide coatings (silicon oxide or aluminium oxide) give much better barriers than the base film at a fraction of the metal content of foil.

Laminates and coextrusions

No single material has every property a package needs, so flexible packages are built from several layers. A laminate joins separate webs with adhesive or by extrusion lamination; a coextrusion forms several polymer layers together from multiple extruders through one die, using tie layers where the polymers do not bond naturally. Each layer does a job: an outer layer for printing, stiffness and abrasion resistance (PET, BOPP, paper); a barrier layer (aluminium foil, metallised film, EVOH, PVDC); and an inner sealant layer that melts and bonds to itself (LDPE, LLDPE, ionomer, cast PP). Typical structures include PET/aluminium foil/cast PP for retort pouches, PET/metallised film/PE for snack packs, and paperboard/PE/aluminium foil/PE for aseptic cartons.

Remember

11. 11. Barrier properties and shelf life of packages

Permeation

Gases and vapours pass through a continuous polymer film by permeation, a three-step process: the permeant dissolves in the film surface on the high-concentration side, diffuses through the film, and desorbs from the other surface. For a film of thickness x, area A and a partial-pressure difference Δp, Fick's first law combined with Henry's law gives the steady-state transmission rate q = P·A·Δp/x, where the permeability coefficient P equals the diffusion coefficient D times the solubility coefficient S. Permeation also occurs by leakage through pinholes, cracks and poor seals, which is not proportional to thickness and is often the real limit of a package. Permeability depends strongly on temperature, generally following an Arrhenius relation, so the barrier of a film at 38 °C is much poorer than at 23 °C.

WVTR and OTR

Packaging barrier is usually quoted as a transmission rate for a stated film under stated conditions rather than as a permeability coefficient. The water vapour transmission rate (WVTR) is the mass of water vapour passing through unit area of the film per day, in g m⁻² day⁻¹, at a stated temperature and relative-humidity difference; test standards specify conditions, commonly including a tropical condition of 38 °C and 90 per cent relative humidity on one side. The oxygen transmission rate (OTR) is the volume of oxygen passing per unit area per day, in cm³ m⁻² day⁻¹ (often per atmosphere of partial-pressure difference), at a stated temperature and humidity. Because a transmission rate is for a particular thickness and condition, three conversions are used. For a homogeneous film, transmission rate is inversely proportional to thickness, so doubling the thickness halves the WVTR. At the same temperature, the rate is proportional to the vapour-pressure difference, so a WVTR measured across a 90 per cent humidity difference can be scaled to a 60 per cent difference by the ratio 60/90. For a multilayer structure without defects, the layers act like resistances in series, so 1/TR_total = Σ(1/TR_i), where each TR_i is the rate of that layer alone under the same conditions; the total is dominated by the best barrier layer.

Shelf life of moisture-sensitive foods

A dry food such as a biscuit, snack or milk powder fails when it has gained enough moisture to lose crispness, cake or support deterioration; the critical moisture content is found by sensory or physical tests. The simplest shelf-life estimate assumes the vapour-pressure driving force stays constant, which is reasonable when the product's water activity stays far below the outside humidity. Then the moisture gained per day is WVTR (corrected to the storage conditions) times package area, and shelf life θ = Ws·(mc − mi)/(WVTR·A), where Ws is the mass of dry solids, mi and mc the initial and critical moisture contents on a dry basis, and A the package area. A more exact method recognises that as the product gains moisture its water activity rises and the driving force falls. If the sorption isotherm is approximately linear over the range, m = b·aw + c, the driving force is proportional to (me − m), where me is the moisture in equilibrium with the outside humidity, and integration gives ln[(me − mi)/(me − mc)] = (P/x)·(A/Ws)·(p0/b)·θ, where P/x is the film permeance and p0 the saturation vapour pressure at the storage temperature. This logarithmic model always predicts a longer shelf life than the constant-rate model for the same data, because it accounts for the falling driving force.

Oxygen, light and aroma

Oxygen-sensitive foods, such as nuts, roasted coffee, fried snacks and fat-rich powders, fail by oxidation. Shelf life is estimated similarly by comparing the oxygen the product can take up before becoming rancid with the oxygen entering through the package and present in the headspace at sealing; this is why such foods are packed in high-barrier materials after nitrogen flushing or vacuum packing, sometimes with oxygen absorbers such as iron-based sachets. Accelerated shelf-life testing stores packs at higher temperature and humidity and extrapolates to normal conditions, which is valid only when the deterioration mechanism does not change with temperature.

Remember

12. 12. Packaging machines, conveyors and elevators

Filling and weighing machines

Packaging lines combine filling, forming, sealing, closing, coding, inspection and grouping. Fillers are chosen by the product. Volumetric fillers meter a set volume: cup fillers for free-flowing granules such as sugar and rice, auger fillers that dispense a set number of screw turns for powders such as flour and milk powder, and piston fillers for liquids and pastes. Their accuracy depends on constant bulk density, so they are often combined with check-weighing. Gravimetric fillers weigh each charge: net-weigh fillers weigh the product before it enters the pack, and multihead combination weighers, used for snacks, frozen foods and confectionery, have many small weigh buckets and a computer that chooses the combination of buckets whose total is closest to the target, giving high accuracy for irregular pieces. Because declared net quantity must be met under legal metrology rules, fillers are set so that the mean fill exceeds the declared quantity by a margin related to the standard deviation of fill; how much underfill is permitted is set by national law. Check-weighers reject packs outside limits, and metal detectors or X-ray inspection reject packs containing foreign bodies.

Form-fill-seal, sealing and closing machines

Form-fill-seal (FFS) machines make the pack from a reel of flexible film, fill it and seal it in one machine. In a vertical FFS machine the film is drawn over a forming collar and around a tube, sealed longitudinally by a fin or lap seal, sealed across at the bottom by the transverse jaws, filled from above by a weigher or auger, and sealed across at the top, the top seal of one bag forming the bottom of the next; it suits granules, powders and snacks. Heat sealing melts the sealant layers under temperature, pressure and time: constant-heat (hot-bar or jaw) sealers for most films, impulse sealers, in which a resistance wire is heated briefly and cools under pressure, for polyethylene, band sealers for continuous pouches, and ultrasonic and induction sealing for special cases, induction being used to seal foil liners inside bottle caps. Line speed is set by the slowest machine, and buffers between machines absorb short stoppages.

Belt, screw and chain conveyors

Belt conveyors carry grain and bags over long distances at high capacity with little damage. Capacity is Q = A·v·ρb, where A is the cross-sectional area of the material on the belt, v the belt speed and ρb the bulk density; troughing the belt with inclined side idlers increases A. Belt inclination is limited by the tendency of the material to slide back, which depends on the material and the belt surface. Power is the sum of the power to lift the material (mass flow × g × lift height), to move the material horizontally and to overcome idler and belt friction; standards and manufacturers' handbooks give the friction factors. Screw conveyors (augers) move material by a rotating helical flight in a trough or tube. Their capacity is Q = (π/4)(D² − d²)·p·N·ρb·φ, where D is the flight diameter, d the shaft diameter, p the pitch, N the speed in revolutions per unit time, and φ the loading efficiency, the fraction of the swept volume actually filled, which is well below one for horizontal troughs and falls further when the conveyor is inclined. Screws are compact, enclosed and can mix, but they need much more power per tonne than belts and can damage grain. Chain and flight conveyors, including en-masse conveyors in which the material moves as a continuous mass in an enclosed casing, handle grain gently at moderate capacity and are common in grain terminals.

Bucket elevators and pneumatic conveyors

Bucket elevators lift grain vertically with buckets attached to a belt or chain running over a head pulley and a boot pulley. Capacity is the bucket volume times the fill fraction times bulk density times the number of buckets passing per second, which equals belt speed divided by bucket spacing. In centrifugal discharge elevators, which run fast with spaced buckets and suit free-flowing grain, the grain is thrown from the buckets as they pass over the head pulley. Discharge is clean when the centrifugal acceleration at the bucket equals or exceeds gravity at the top of the pulley: ω²r = g, so v²/r = g with r the effective radius to the centre of mass of the bucket load. Taking r as the pulley radius, the speed at which this happens is N = (60/2π)·√(g/r) = 42.3/√D revolutions per minute for a pulley of diameter D in metres, and the head pulley is run near this speed; too slow and the grain falls back down the leg, too fast and it is thrown against the head casing. The power to lift material is mass flow × g × lift, divided by the drive efficiency, plus an allowance for scooping in the boot. Pneumatic conveyors move grain or powder in a pipeline by air. In dilute-phase conveying the particles are suspended in a high-velocity air stream, which must exceed the saltation velocity at which particles settle out in horizontal pipes; in dense-phase conveying the material moves slowly as plugs or dunes at high pressure with less damage and wear.

Remember

What the exams ask

How it is used, across a career

As a student

A student uses this subject to solve the standard problems cleanly: compute hydraulic radius, Rankine's k and the shallow-or-deep test before choosing an equation; apply Janssen with the correct units (γ in N/m³ not kg/m³); find silo capacity including the cone of repose; set a bucket-elevator head-pulley speed; scale a WVTR for thickness and humidity; and estimate shelf life. The same student should be able to name the primary and secondary storage insects, describe moisture migration with a sketch, explain why EVOH is sandwiched between polyolefins, and say why phosphine fumigation fails in a leaky store. Those are the items that recur across GATE, ICAR and university examinations.

Five years in

An engineer five years into practice sizes aeration fans for a farm or cooperative bin from the airflow per tonne, grain depth and airflow-resistance data; checks a supplier's bin wall and foundation design against the grain-load standard; lays out a godown or warehouse with stack plots, gangways and rodent proofing; writes a fumigation plan with sealing, pressure-decay testing, gas monitoring and re-entry checks; specifies conveyors and elevators for a receiving pit and a mill; and for a food plant selects a film structure and filler for a new product and runs a shelf-life test. Most of the work is judgement about what the numbers mean on site: dirty grain, a leaking silo, a pack stored hotter than planned.

Twenty-five years in

A senior engineer with twenty-five years' experience plans storage capacity for a region or a procurement agency: the mix of silos, godowns and temporary storage, their locations, the conveying and aeration systems, and the operating rules that keep losses low. Such a person investigates silo failures (eccentric discharge, overpressure during emptying, corroded or buckled walls), dust explosions and fumigation accidents, and writes the procedures that prevent them. They negotiate standards and contracts for storage services and warehouse receipts, weigh the cost of moving from bag to bulk handling, and decide on the replacement of phosphine-only regimes with integrated pest management and sealed storage as resistance spreads. In packaging they lead line specification and supplier qualification.

PhD, twenty-five years in

A researcher with a doctorate and long experience works on the open problems: discrete-element and continuum models of granular flow and wall pressure in silos, including dynamic loads and switch pressures; sensor networks (temperature, carbon dioxide, moisture) and models that predict spoilage in stored grain; phosphine resistance management and alternative fumigants and atmospheres; hermetic storage for smallholders and its economics; aeration control strategies driven by weather data; high-barrier recyclable monomaterial films, active and intelligent packaging, and shelf-life models that couple moisture, oxygen and temperature histories. Such a person also trains others, reviews standards, and translates field evidence on post-harvest losses into policy.

Written from

This manual does not give Airy's deep-bin formula, because its form differs between textbooks and could not be checked with certainty; use Janssen's equation for deep bins. It does not reproduce the design coefficients, overpressure factors, packing factors or airflow-resistance constants of the ASABE standards, which must be taken from the current edition. It gives no fumigant doses, exposure periods, occupational exposure limits or re-entry concentrations, because these are set by product labels and national regulators and change. Recommended aeration airflows, safe storage moistures, godown plinth heights and stack dimensions are described but not tabulated because they vary by crop, climate and agency. CA gas compositions for individual fruit cultivars, silo seismic and wind design, concrete silo detailing, and food-contact migration regulations are not covered in detail.

Original practice questions written to the syllabus and pattern of the exams named in each question's examTags. They are not past papers and do not reproduce any board's questions. Every numerical answer was computed by script; property values in numerical questions are illustrative and vary by crop, material and standard.

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