LAISHA · DRAVYAGUNA

Sphatika

स्फटिक

Potassium aluminium sulphate dodecahydrate, KAl(SO4)2·12H2O.

Parthiva · mineral origin · Sadharana rasa / Kshara

SHODHANA — NO MINERAL DRAVYA IS USED RAW

Heated until it melts and puffs into a light white mass — sphatika bhasma. The raw crystal is used externally; the puffed form internally.

Benefits & side effects

TRADITIONAL VIEW, WITH SAFETY LIMITS

Hindi name: Phitkari

What the texts say Sphatika does

What the evidence says. Alum's astringent and antimicrobial action is established; the internal classical uses are not.

Side effects and limits

Aluminium-bearing, and chronic aluminium exposure matters in renal impairment because the kidney is how aluminium leaves. Concentrated alum is a mucosal irritant.

Avoid or ask first: Renal impairment — aluminium accumulates.; Prolonged internal use.

A traditional classification, not a recommendation. The full safety record is below.

Matra and anupana

AS THE CLASSICAL TEXTS AND THE API PRESCRIBE

Bhasma125–250 mg
AnupanaMadhu · Ushnodaka
KalaAdhobhakta

Chiefly external — as a styptic, a gargle and a wash. Internal use is small and short.

Reported from Sharangadhara Samhita and the Ayurvedic Pharmacopoeia of India. Laisha states what the texts prescribe; it does not recommend. No quantity here is adjusted for a particular person — not for agni, koshtha, bala, age, pregnancy, kidney or liver function, or anything already being taken.

Rasapanchaka

Rasa
KashayaAmlaMadhura
Guna
LaghuRuksha
ViryaUshna
VipakaKatu
DoshakarmaKaphapittahara.

Karma and part used

StambhanaVranashodhanaRaktastambhanaKrimighna
Upayukta angaSphatika bhasma for internal use; the raw crystal externally

Paryaya

SurashtrajaTuvarikaKamakshi

Sphatika is classed among the Sadharana rasa / Kshara.

Names, by language

EnglishPotash alum
HindiPhitkari
KannadaPatika

Classical references

Rasa Ratna Samuccaya
Chapter 3
Among the sadharana rasa; gives its shodhana and uses.
Bhavaprakasha Nighantu
Dhatvadi Varga
Rasa, guna and its stambhana action.

Rasa, guna, virya, vipaka and karma are recorded as the classical texts give them, with the text and section named so a student can open the book and check.

Adulterants and substitutes

Ammonium alum is sold as phitkari and is not the same salt as potash alum.

Identity

Potassium aluminium sulphate dodecahydrate, KAl(SO4)2·12H2O.

A WAY TO REMEMBER IT

Sphatika means crystal or quartz in Sanskrit, and was given to alum for its clear crystalline habit. Alum is from the Latin alumen, which also gives us aluminium.

What the tradition holds

Sphatika is the classical styptic and is used in raktapitta, in vrana and as a gargle in mukha roga.

Constituents. Potassium aluminium sulphate dodecahydrate, KAl(SO4)2·12H2O.

What the evidence says

StatusAlum's astringent and antimicrobial action is established; the internal classical uses are not.
The honest gapMineral and animal dravya are far less studied than plant dravya, and what study exists is chiefly characterisation and toxicology rather than clinical efficacy.

Safety

Aluminium-bearing, and chronic aluminium exposure matters in renal impairment because the kidney is how aluminium leaves. Concentrated alum is a mucosal irritant.

ContraindicationsRenal impairment — aluminium accumulates.
Prolonged internal use.
InteractionsAny oral drug — aluminium binds in the gut. Separate by two hours, as for any antacid.
Tetracyclines, fluoroquinolones and bisphosphonates — absorption reduced.
Citrate, in any form, sharply increases aluminium absorption. This is the interaction most often missed.
Pregnancy and breastfeedingNot established as safe internally. External use is unremarkable.

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What this is not

Sources

Rasa Ratna Samuccaya and Rasa Tarangini
National Institute of Indian Medical Heritage
The classical Rasashastra position: which group the dravya belongs to, its shodhana and marana, and the matra of the prepared form.
https://niimh.nic.in/ebooks/
Ayurvedic Pharmacopoeia of India
Pharmacopoeia Commission for Indian Medicine and Homoeopathy, Ministry of Ayush, Government of India
The official Indian pharmacopoeial standing of the dravya and the identity of the prepared article.
https://pcimh.gov.in/
Classical matra by dose form
Sharangadhara Samhita, Madhyama Khanda
The classical quantity for each dose form, as the standard reference gives it.
https://niimh.nic.in/ebooks/esharangadhara/
Safety of aluminium from dietary intake
European Food Safety Authority (EFSA)
The tolerable weekly intake for aluminium and the reason renal impairment is a contraindication.
https://www.efsa.europa.eu/en/efsajournal/pub/754
Toxicological profile
Agency for Toxic Substances and Disease Registry (ATSDR)
The toxicology of the element itself — route, accumulation, target organ and the exposure at which harm is documented.
https://www.atsdr.cdc.gov/toxprofiledocs/index.html
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