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CUET-PG Environmental Chemistry: practice questions

CUET-PG — Environmental Sciences · India · National Testing Agency

Original practice questions written to the published syllabus · not past papers
10worked here, free
36written to this exam in this subject
13syllabus units

What this subject covers

The chemistry of water, soil and air that pollution, treatment and climate subjects assume: equilibria, the carbonate system, redox, gas solubility, ozone and smog chemistry. GATE ES Section 2 in full.

In the exams: GATE ES Section 2; UGC NET Environmental Sciences Unit 2; ICAR AIEEA-PG Physical Science Unit II (chemistry)

What CUET-PG asks from it

CUET-PG Environmental Sciences and CSIR-UGC NET (Earth, Atmospheric, Ocean and Planetary Sciences)

Carbonate chemistry and ocean acidification, atmospheric composition and ozone chemistry, and basic equilibrium and redox principles.

Where the 36 questions fall

How our questions for CUET-PG spread across the units of Environmental Chemistry. Difficulty: 16 easy, 20 medium, 0 hard.

Chemical bonding, concentration units, activity and ionic strength5
Acid-base equilibria, buffers and alkalinity4
Chemical equilibrium, thermodynamics and reaction kinetics3
The carbonate system and ocean acidification3
Solubility of gases in water: Henry's law3
Complexation, precipitation and solubility product3
Redox reactions, pe-pH diagrams and redox zonation3
Water quality parameters and their measurement3
Radioactivity and radionuclides in the environment3
Speciation of inorganic and organic contaminants2
Composition and structure of the atmosphere2
Tropospheric ozone and photochemical smog1
Stratospheric ozone chemistry and ozone-depleting substances1

10 practice questions, worked

Choose an answer, then open the working. Each explanation says why the right answer is right and why the others are not.

1 · Chemical bonding, concentration units, activity and ionic strength · medium

What is the ionic strength of a 0.01 M CaCl2 solution?

  1. 0.03 M
  2. 0.05 M
  3. 0.02 M
  4. 0.01 M
Answer and working

A. 0.03 M

I = ½(0.01 × 2² + 0.02 × 1²) = ½(0.04 + 0.02) = 0.03 M. 0.01 is the salt concentration; 0.02 ignores charge squared for Ca; 0.05 omits the ½.

Further reading: See the manual sources: Sawyer, McCarty & Parkin; Manahan; Stumm & Morgan; Seinfeld & Pandis; IS 10500; WMO/UNEP ozone assessment

2 · Acid-base equilibria, buffers and alkalinity · medium

An acetate buffer contains 0.2 M acetate and 0.1 M acetic acid (pKa 4.76). What is its pH?

  1. 4.46
  2. 5.06
  3. 4.76
  4. 5.76
Answer and working

B. 5.06

pH = pKa + log([A⁻]/[HA]) = 4.76 + log 2 = 5.06. 4.76 assumes equal amounts; 4.46 inverts the ratio; 5.76 adds one full unit.

Further reading: See the manual sources: Sawyer, McCarty & Parkin; Manahan; Stumm & Morgan; Seinfeld & Pandis; IS 10500; WMO/UNEP ozone assessment

3 · Solubility of gases in water: Henry's law · easy

How does the saturation concentration of dissolved oxygen in water change as temperature rises?

  1. It first rises then falls above 10 °C
  2. It increases
  3. It stays the same
  4. It decreases
Answer and working

D. It decreases

Gas solubility falls with temperature: about 14.6 mg/L at 0 °C, 9.1 at 20 °C and 7.6 at 30 °C.

Further reading: See the manual sources: Sawyer, McCarty & Parkin; Manahan; Stumm & Morgan; Seinfeld & Pandis; IS 10500; WMO/UNEP ozone assessment

4 · Complexation, precipitation and solubility product · medium

Why do amphoteric metal hydroxides such as Al(OH)3 redissolve at very high pH?

  1. They react with dissolved oxygen to form gases
  2. They lose all water and become oxides that dissolve
  3. They are reduced to the metal at high pH
  4. They form soluble hydroxo-anions such as aluminate
Answer and working

D. They form soluble hydroxo-anions such as aluminate

Amphoteric hydroxides dissolve in strong base as aluminate and similar anions, so each metal has a pH of minimum solubility.

Further reading: See the manual sources: Sawyer, McCarty & Parkin; Manahan; Stumm & Morgan; Seinfeld & Pandis; IS 10500; WMO/UNEP ozone assessment

5 · Redox reactions, pe-pH diagrams and redox zonation · medium

On a pe–pH diagram for iron, which form is stable under oxidising, near-neutral conditions?

  1. Insoluble ferric oxyhydroxides
  2. Metallic iron
  3. Dissolved Fe³⁺ ions at high concentration
  4. Dissolved Fe²⁺ ions
Answer and working

A. Insoluble ferric oxyhydroxides

Oxidising, neutral conditions favour Fe(III) solids; reducing or acidic conditions favour soluble Fe²⁺.

Further reading: See the manual sources: Sawyer, McCarty & Parkin; Manahan; Stumm & Morgan; Seinfeld & Pandis; IS 10500; WMO/UNEP ozone assessment

6 · Redox reactions, pe-pH diagrams and redox zonation · medium

What is the oxidation state of sulphur in sulphate (SO4²⁻)?

  1. −2
  2. +6
  3. +2
  4. +4
Answer and working

B. +6

S + 4(−2) = −2, so S = +6. Sulphide is −2; sulphite +4.

Further reading: See the manual sources: Sawyer, McCarty & Parkin; Manahan; Stumm & Morgan; Seinfeld & Pandis; IS 10500; WMO/UNEP ozone assessment

7 · Speciation of inorganic and organic contaminants · medium

Which mercury species is most toxic and bioaccumulative, causing Minamata disease?

  1. Mercury(I) chloride
  2. Mercury(II) sulphide
  3. Methylmercury
  4. Elemental mercury vapour
Answer and working

C. Methylmercury

Methylmercury biomagnifies in fish and caused Minamata disease in Japan in the 1950s.

Further reading: See the manual sources: Sawyer, McCarty & Parkin; Manahan; Stumm & Morgan; Seinfeld & Pandis; IS 10500; WMO/UNEP ozone assessment

8 · Water quality parameters and their measurement · easy

Which parameter measures the oxygen required to chemically oxidise organic matter using potassium dichromate?

  1. Chemical oxygen demand (COD)
  2. Total organic carbon (TOC)
  3. Dissolved oxygen (DO)
  4. Biochemical oxygen demand (BOD)
Answer and working

A. Chemical oxygen demand (COD)

COD uses dichromate in acid; BOD is microbial oxygen use over 5 days; DO is dissolved oxygen; TOC measures carbon.

Further reading: See the manual sources: Sawyer, McCarty & Parkin; Manahan; Stumm & Morgan; Seinfeld & Pandis; IS 10500; WMO/UNEP ozone assessment

9 · Stratospheric ozone chemistry and ozone-depleting substances · easy

Which international agreement controls the production of ozone-depleting substances such as CFCs?

  1. The Stockholm Convention (2001)
  2. The Kyoto Protocol (1997)
  3. The Montreal Protocol (1987)
  4. The Basel Convention (1989)
Answer and working

C. The Montreal Protocol (1987)

Montreal regulates ODS; Kyoto greenhouse gases; Stockholm POPs; Basel hazardous waste trade.

Further reading: See the manual sources: Sawyer, McCarty & Parkin; Manahan; Stumm & Morgan; Seinfeld & Pandis; IS 10500; WMO/UNEP ozone assessment

10 · Radioactivity and radionuclides in the environment · medium

Which type of radiation is stopped by a sheet of paper but is most hazardous when inhaled or ingested?

  1. Alpha particles
  2. X-rays
  3. Beta particles
  4. Gamma rays
Answer and working

A. Alpha particles

Alpha particles have low penetration but high ionisation; inside the body they damage tissue intensely.

Further reading: See the manual sources: Sawyer, McCarty & Parkin; Manahan; Stumm & Morgan; Seinfeld & Pandis; IS 10500; WMO/UNEP ozone assessment

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Read the subject

Environmental ChemistryThe full study manual, free CUET-PGFormat, sections and how it has changed

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